NR 140.14(3)(b)1.1. The substance has been analytically confirmed to be present in the same sample using an equivalently sensitive analytical method or the same analytical method, and NR 140.14(3)(b)2.2. The substance has been statistically confirmed to be present above the preventive action limit or enforcement standard, determined by an appropriate statistical test with sufficient samples at a significance level of 0.05. NR 140.14(3)(c)(c) If the preventive action limit or enforcement standard is between the limit of detection and the limit of quantitation, the regulatory agency shall consider the preventive action limit or enforcement standard to be attained or exceeded if the concentration of a substance is reported at or above the limit of quantitation. NR 140.14 HistoryHistory: Cr. Register, September, 1985, No. 357, eff. 10-1-85; am. (1) (intro.) and (b), r. and recr. (2), Register, October, 1988, No. 394, eff. 11-1-88; am. (1) (b), (2) and (3) (b), Register, September, 1990, No. 417, eff. 10-1-90; am. (1) (b), Register, March, 1994, No. 459, eff. 4-1-94; r. and recr. (3) (intro.), (a), (b), renum. (3) (c) to be 140.16 (5) and am., Register, August, 1995, No. 476, eff. 9-1-95. NR 140.16NR 140.16 Monitoring and laboratory data requirements. NR 140.16(1)(a)(a) All groundwater quality samples collected to determine compliance with ch. 160, Stats., shall comply with this section except as noted. NR 140.16(1)(b)(b) Groundwater sampling requirements. All groundwater quality samples shall be collected and handled in accordance with procedures specified by the applicable regulatory agency or, where no sampling procedures are specified by that agency, in accordance with the sampling procedures referenced in par. (c). The sampling procedures specified by a regulatory agency may include requirements for field filtration. NR 140.16(1)(c)1.1. If sampling procedures are not specified by the applicable regulatory agency pursuant to par. (b), all groundwater quality samples shall be collected and handled in accordance with the sampling procedures contained in the following publications: NR 140.16(1)(c)1.a.a. Groundwater Sampling Desk Reference. Wisconsin Department of Natural Resources, PUBL-DG-037-96, September, 1996. NR 140.16(1)(c)1.b.b. Groundwater Sampling Field Manual. Wisconsin Department of Natural Resources, PUBL-DG-038-96, September, 1996. NR 140.16 NoteNote: Copies of these publications may be purchased from:
NR 140.16 NoteWisconsin Department of Administration
Document Sales Unit
4622 University Avenue
Madison, WI 53705-2156
NR 140.16 NoteThese publications are available for inspection at the offices of the department, the secretary of state and the legislative reference bureau.
NR 140.16(1)(c)2.2. Where no procedure for collecting a particular groundwater quality sample is specified by the appropriate regulatory agency or in the publications referenced in subd. 1., other published scientifically valid groundwater sampling procedures may be used. NR 140.16(1)(d)(d) Laboratory requirements.. All groundwater quality samples, except samples collected for total coliform bacteria laboratory analysis, E. coli laboratory analysis, field analyses for pH, field analysis for specific conductance, and field analysis for temperature, shall be analyzed in accordance with provisions under ch. NR 149 by a laboratory certified or registered under ch. NR 149. Samples for total coliform bacteria and E. coli analysis shall be analyzed by the state laboratory of hygiene or at a laboratory approved or certified by the department of agriculture, trade and consumer protection. NR 140.16 NoteNote: Refer to s. NR 149.442 for sample preservation procedures and holding times. NR 140.16(1)(e)(e) Data submittal. The results of the analysis of groundwater quality samples shall be submitted to the department and any applicable regulatory agency. Except as provided in s. NR 205.07 (3) (c) for wastewater permittees, this section does not require the submission of groundwater monitoring data which is collected voluntarily and is not required to be collected to determine compliance with this chapter or another rule or statute. NR 140.16(2)(2) The laboratory shall select the analytical methodology which: NR 140.16(2)(a)(a) Is specified in rules or approved by the regulatory agency, and NR 140.16(2)(c)1.1. Has a limit of detection and limit of quantitation below the preventive action limit, or NR 140.16(2)(c)2.2. Produces the lowest available limit of detection and limit of quantitation if the limit of detection and limit of quantitation are above the preventive action limit. NR 140.16(3)(3) If the owner or operator of a facility, practice or activity believes that a sample result does not represent groundwater quality in the vicinity of the facility, practice or activity, the owner or operator shall resample the appropriate well or wells to obtain a representative sample at the earliest possible time. All sample results shall be submitted to the department and the appropriate regulatory agency with an explanation of why the owner or operator believes that all or some of the results are invalid. NR 140.16(4)(4) The department may reject groundwater quality data that does not meet the requirements of the approved or designated analytical methods. NR 140.16(5)(5) The owner or operator of the facility, practice or activity shall report the limit of detection and the limit of quantitation with the sample results. If a substance is detected below the limit of quantitation, the owner or operator shall report the detected value with the appropriate qualifier to the regulatory agency. NR 140.16 HistoryHistory: Cr. Register, September, 1985, No. 357, eff. 10-1-85; am. (1), Register, September, 1990, No. 417, eff. 10-1-90; am. (1), r. and recr. (2), Register, March, 1994, No. 459, eff. 4-1-94; (5) renum. from NR 140.14 (3) (c), cr. (4), Register, August, 1995, No. 476, eff. 9-1-95; r. and recr. (1), Register, December, 1998, No. 516, eff. 1-1-99; CR 22-061: am. (1) (d) Register July 2023 No. 811, eff. 8-1-23. NR 140.20NR 140.20 Indicator parameter groundwater standards. NR 140.20(1)(1) Establishing background water quality. Background water quality at a facility, practice or activity at which monitoring is required shall be established by sampling one or more monitoring points at locations and depths sufficient to yield groundwater samples that are representative of background water quality at or near the facility, practice or activity. Background water quality shall be determined for indicator parameters specified by the department. Background water quality for indicator parameters shall be established by averaging a minimum of 8 sample results from each well. The department may exclude any sample result which is nonrepresentative of background water quality. In making the calculations required in this section, the department may use as many representative sample points as are available. NR 140.20(2)(2) Establishing preventive action limits for indicator parameters. For each indicator parameter, except total coliform bacteria, for which groundwater monitoring is required by the department, the preventive action limit shall be established based upon a change of water quality with respect to background water quality according to the methodology specified in any of the following: NR 140.20(2)(a)(a) For field pH, the preventive action limit shall be one pH unit above or below the pH of the background water quality. NR 140.20(2)(b)(b) For field temperature, the preventive action limit shall be 3 standard deviations or 10ºF (5.6ºC), whichever is greater, above or below the temperature of the background water quality. NR 140.20(2)(c)(c) For all other indicator parameters, the preventive action limit shall be the background water quality for that parameter plus 3 standard deviations or the background water quality plus the increase of that parameter listed in Table 3, whichever is greater. NR 140.20 NoteNote: The standard deviation for a group of samples is equal to the square root of: the value of the sum of the squares of the difference between each sample in the sample group and the mean for that sample group divided by the number of samples in the sample group where the sample group has 30 or more samples and by one less than the number of samples in the sample group where the sample group has less than 30 samples.
NR 140.20(3)(3) Total coliform bacteria indicator parameter. The preventive action limit for total coliform bacteria is 0. If the source of total coliform bacteria is determined to be from a regulated facility, practice, or activity, response actions under s. NR 140.24 may be required. Table 3
Methodology for Establishing Preventive Action Limit for Indicator Parameters
NR 140.20 HistoryHistory: Cr. Register, September, 1985, No. 357, eff. 10-1-85; am. table 3, Register, October, 1990, No. 418, eff. 11-1-90; am. Table 3, Register, December, 1998, No. 516, eff. 1-1-99; CR 09-102: am. Table 3 Register December 2010 No. 660, eff. 1-1-11; CR 22-061: am. (2) (intro.), cr. (3), am. Table 3 Register July 2023 No. 811, eff. 8-1-23. NR 140.22NR 140.22 Point of standards application for design and compliance. NR 140.22(1)(1) Design. Except as specified in sub. (1m), facilities, practices or activities regulated by the department, including remedial actions, shall be designed to minimize the level of substances in groundwater and to comply with the preventive action limits to the extent technically and economically feasible at all the following locations: NR 140.22(1)(b)(b) Any point beyond the boundary of the property on which the facility, practice or activity is located. NR 140.22(1)(c)(c) Any point within the property boundaries beyond the 3-dimensional design management zone if one is established by the department at each facility, practice or activity under sub. (3). NR 140.22(1)(d)(d) Every point at which groundwater is monitored to determine if a preventive action limit or enforcement standard has been attained or exceeded for sites identified under s. NR 140.22 (2) (c). NR 140.22(1m)(1m) Design of asr systems; specified substances. The point of standards application to determine if the design of an aquifer storage recovery system, regulated under ch. 280 or 281, Stats., complies with the preventive action limits for a specified substance is 1,200 feet from an aquifer storage and recovery well and at any other well that is not part of the ASR system and that is within 1,200 feet of an aquifer storage recovery well. NR 140.22(2)(a)(a) Except as specified in par. (d), the point of standards application to determine if a preventive action limit has been attained or exceeded is any point at which groundwater is monitored. NR 140.22(2)(b)(b) Except as specified in par. (d), the point of standards application to determine whether an enforcement standard has been attained or exceeded shall be the following locations: NR 140.22(2)(b)2.2. Any point beyond the boundary of the property on which the facility, practice or activity is located; NR 140.22(2)(b)3.3. Any point within the property boundaries beyond the 3 dimensional design management zone if one is established by the department at each facility, practice or activity under sub. (3). NR 140.22 NoteNote: The boundary beyond which the enforcement standards apply is the closer of the property boundary or the design management zone boundary to the waste boundary for the facility, practice or activity.
NR 140.22(2)(c)(c) For discharges, releases, sites or facilities regulated under s. 292.11, 291.29 or 291.37, Stats., or s. NR 600.07, for which a design management zone has not been established in sub. (3), Table 4, the point of standards application shall be every point at which groundwater is monitored to determine if a preventive action limit or enforcement standard has been attained or exceeded. NR 140.22 NoteNote: Section NR 600.07 no longer exists.
NR 140.22(2)(d)(d) The point of standards application to determine if a preventive action limit or enforcement standard for a specified substance has been attained or exceeded at an aquifer storage recovery well, regulated under ch. 280 or 281, Stats., is 1,200 feet from the aquifer storage and recovery well and at any other well that is not part of the ASR system and that is within 1,200 feet of the aquifer storage recovery well. NR 140.22(3)(a)(a) The design management zone for facilities, practices or activities subject to regulation by the department shall be an area enclosed by vertical boundaries which extend from the land surface downward through all saturated geological formations. The design management zone shall extend horizontally beyond the waste boundary or ASR displacement zone to the distance indicated in Table 4 for the specific type of facility, practice or activity. The waste boundary shall be the outermost limit at which waste from a facility, practice or activity has been stored, applied or disposed of, or permitted or approved for storage, application or disposal. For hazardous waste facilities regulated under ch. 291, Stats., the waste boundary shall include the horizontal space taken up by any liner, dike or other barrier to contain waste. NR 140.22(3)(b)(b) In issuing or reissuing a permit, license or approval, the department may consider an expansion or reduction of the design management zone at a regulated or proposed facility, practice or activity by a horizontal distance not to exceed 50% of the distance listed in Table 4. NR 140.22(3)(c)(c) The department shall consider the following factors in determining whether to expand or reduce the design management zone: NR 140.22(3)(c)1.1. Nature, thickness and permeability of unconsolidated materials, including topography; NR 140.22(3)(c)4.4. Waste volume, waste type and characteristics, including waste loading; NR 140.22(3)(d)(d) The design management zone may not be expanded or reduced unless it has been demonstrated to the satisfaction of the department that the preventive action limits and enforcement standards will be met at the adjusted design management zone. The design management zone may not be expanded unless it has been demonstrated to the satisfaction of the department that the preventive action limits and enforcement standards cannot be met at the design management zone specified in Table 4. Table 4
NR 140.22 HistoryHistory: Cr. Register, September, 1985, No. 357, eff. 10-1-85; am. (1) (b), Register, October, 1988, No. 394, eff. 11-1-88; am. (4) and table 4, Register, January, 1992, No. 433, eff. 2-1-92; am. (1), cr. (1) (d), renum. (2) to (5) to be (2) (a), (b), (c) and (3) and am. (2) (b) 3., Register, March, 1994, No. 459, eff. 4-1-94; CR 02-134: am. (1) (intro.), (2) (a), (b) (intro.), (3) (a) and Table 4, cr. (1m) and (2) (d) Register June 2003 No. 570, eff. 7-1-03; correction in Table 4 made under s. 13.93 (2m) (b) 7., Stats., Register November 2006 No. 611. NR 140.24NR 140.24 Responses when a preventive action limit is attained or exceeded. NR 140.24(1)(1) Notification and assessment. If the concentration of a substance, including indicator parameters, in groundwater attains or exceeds a preventive action limit at a point of standards application as described in s. NR 140.22 (2): NR 140.24(1)(a)(a) The owner or operator of the facility, practice or activity shall notify the department in writing when monitoring data is submitted that a preventive action limit has been attained or exceeded in accordance with any deadlines in applicable statutes, rules, permits or plan approvals. Where no deadlines are imposed, the owner or operator shall notify the department as soon as practical after the results are received. When the results of any private well sampling attain or exceed a preventive action limit, the owner or operator of the facility, practice or activity shall notify the department within 10 days after the results are received. The notification shall provide a preliminary analysis of the cause and significance of the concentration. NR 140.24 NoteNote: Section 292.11 (2) (a), Stats., requires that the department be notified immediately of hazardous substance discharges. NR 140.24(1)(b)(b) Upon receipt of the notice under par. (a), the department shall evaluate the information and, if further information is required to make the assessment under par. (c), direct the owner or operator to prepare and submit a report by a specified deadline. The report shall assess the cause and significance of the increased concentration based on a consideration of the factors identified in par. (c) and shall propose a response to meet the objectives of sub. (2). NR 140.24(1)(c)(c) The department shall assess the cause and significance of the concentration of the substance in determining the appropriate response to meet the objectives of sub. (2). In addition to all other relevant information, the department shall consider the information submitted under par. (b) and the following factors where applicable: NR 140.24(1)(c)1.a.a. The department shall compare background water quality data and monitoring data from wells downgradient of the facility, practice or activity to determine if downgradient water quality is adversely affected. If the background water quality at a facility, practice or activity is not known or is inadequately defined, the department may require additional sampling of existing wells, or installation and sampling of additional wells, or both. NR 140.24(1)(c)1.b.b. Except for substances which are carcinogenic, teratogenic or mutagenic in humans, before requiring a response at a site where the background concentration of a substance is determined to be equal to or greater than the preventive action limit, the department shall determine that the proposed remedial action will protect or substantially improve groundwater quality notwithstanding the background concentrations of naturally occurring substances. NR 140.24(1)(c)2.2. Reliability of sampling data. As part of its review of the quality of the sampling data, the department shall evaluate the sampling procedures, precision and accuracy of the analytical test, size of the data set, and the quality control and quality assurance procedures used. If there is insufficient information to evaluate the reliability of the sampling data, the department may require additional samples or other changes in the monitoring program at the facility, practice or activity. NR 140.24(1)(c)3.3. Public health, welfare and environmental effects of the substance. The department shall consider the public health, welfare and environmental effects of the substance, including but not limited to its mobility in the subsurface, environmental fate, the risks considered when the standard was adopted and whether it is carcinogenic, mutagenic, teratogenic or has interactive effects with other substances. NR 140.24(1)(c)4.4. Probability that a preventive action limit or an enforcement standard may be attained or exceeded outside the design management zone. In evaluating the probability that a preventive action limit or an enforcement standard may be attained or exceeded outside the design management zone, the department shall consider, at a minimum, geologic conditions, groundwater flow rate and direction, contaminant mobility in the subsurface and environmental fate.
