82Section 82   NR 666.904 (2) (f) is created to read:
NR 666.904 (2) (f) Make an accurate waste determination according to s. NR 662.011.
_Hlk147409123Section 83   NR 666.904 (5) (c) is amended to read:
NR 666.904 (5) (c) In the event of a fire, explosion, or other release which that could threaten human health or if a spill has reached surface water, immediately notify the national response center, using their its 24-hour toll free number (800)424-8802(800) 424-8802. The notification shall include all of the following information: The name and address of the facility owner, date, time and type of incident, quantity and type of hazardous waste involved in the incident, extent of injuries, if any and estimated quantity and disposition of recovered materials, if any.
84Section 84   NR 666.905 (intro.) is amended to read:
NR 666.905 Transportation requirements. An owner or operator of a collection facility shall ensure delivery of all the hazardous waste to a licensed hazardous waste treatment, storage or disposal facility, legitimate recycling facility under s. NR 660.43, or permanent collection facility, according to the following:
_Hlk153548029Section 85   NR 666.905 (1) (f) is repealed and recreated to read:
NR 666.905 (1) (f) Do all of the following:
1. Use a manifest that consists of at least the number of copies that will provide the collection facility owner or operator, each transporter, the owner or operator of the designated facility, and the department with one copy each for their records and another final, signed copy to be returned to the collection facility owner or operator.
2. Prepare and use a manifest, OMB control number 2050-0039, on EPA Form 8700-22, and if necessary, EPA Form 8700–22A, according to the instructions in the appendix to 40 CFR part 262.
3. Keep a copy of each manifest signed by the collection facility owner or operator and the initial transporter for 3 years or until the facility owner or operator receives a signed copy from the designated hazardous waste facility that received the waste.
4. Retain the final, signed copy of the manifest as a record for at least 3 years from the date the waste was accepted by the initial transporter.
_Hlk153548138Section 86   NR 666.905 (3) (c) is amended to read:
NR 666.905 (3) (c): Under 49 CFR 171.1 (d) (5), governmental employees who self-transport hazardous materials or hazardous waste are exempt from the DOT hazardous materials requirements (including packaging, labeling, marking, placarding, and manifesting) if the transportation is done solely for non-commercial, governmental purposes.
Section 87.   NR 666 Appendix IV Table is amended to read:
Chapter NR 666
APPENDIX IV
REFERENCE AIR CONCENTRATIONS*
Constituent
CAS No.
RAC (ug/m3)
Acetaldehyde
75−07−0
10
Acetonitrile
75−05−8
10
Acetophenone
98−86−2
100
Acrolein
107−02−8
20
Aldicarb
116−06−3
1
Aluminum Phosphide
20859−73−8
0.3
Allyl Alcohol
107−18−6
5
Antimony
7440−36−0
0.3
Barium
7440−39−3
50
Barium Cyanide
542−62−1
50
Bromomethane
74−83−9
0.8
Calcium Cyanide
592−01−8
30
Carbon Disulfide
75−15−0
200
Chloral
75−87−6
2
Chlorine (free)
0.4
2−Chloro−1,3−butadiene
126−99−8
3
Chromium III
16065−83−1
1000
Copper Cyanide
544−92−3
5
Cresols
1319−77−3
50
Cumene
98−82−8
1
Cyanide (free)
57−12−15
20
Cyanogen
460−19−5
30
Cyanogen Bromide
506−68−3
80
Di−n−butyl Phthalate
84−74−2
100
o−Dichlorobenzene
95−50−1
10
p−Dichlorobenzene
106−46−7
10
Dichlorodifluoromethane
75−71−8
200
2,4−Dichlorophenol
120−83−2
3
Diethyl Phthalate
84−66−2
800
Dimethoate
60−51−5
0.8
2,4−Dinitrophenol
51−28−5
2
Dinoseb
88−85−7
0.9
Diphenylamine
122−39−4
20
Endosulfan
115−29−1
0.05
Endrin
72−20−8
0.3
Fluorine
7782−41−4
50
Formic Acid
64−18−6
2000
Glycidyaldehyde
765−34−4
0.3
Hexachlorocyclopentadiene
77−47−4
5
Hexachlorophene
70−30−4
0.3
Hydrocyanic Acid
74−90−8
20
Hydrogen Chloride
7647−01−1
7
Hydrogen Sulfide
7783−06−4
3
Isobutyl Alcohol
78−83−1
300
Lead
7439−92−1
0.09
Maleic Anyhdride Anhydride
108−31−6
100
Mercury
7439−97−6
0.3
Methacrylonitrile
126−98−7
0.1
Methomyl
16752−77−5
20
Methoxychlor
72−43−5
50
Methyl Chlorocarbonate
79−22−1
1000
Methyl Ethyl Ketone
78−93−3
80
Methyl Parathion
298−00−0
0.3
Nickel Cyanide
557−19−7
20
Nitric Oxide
10102−43−9
100
Nitrobenzene
98−95−3
0.8
Pentachlorobenzene
608−93−5
0.8
Pentachlorophenol
87−86−5
30
Phenol
108−95−2
30
M−Phenylenediamine
108−45−2
5
Phenylmercuric Acetate
62−38−4
0.075
Phosphine
7803−51−2
0.3
Phthalic Anhydride
85−44−9
2000
Potassium Cyanide
151−50−8
50
Potassium Silver Cyanide
506−61−6
200
Pyridine
110−86−1
1
Selenious Acid
7783−60−8
3
Selenourea
630−10−4
5
Silver
7440−22−4
3
Silver Cyanide
506−64−9
100
Sodium Cyanide
143−33−9
30
Strychnine
57−24−9
0.3
1,2,4,5−Tetrachlorobenzene
95−94−3
0.3
2,3,4,6−Tetrachlorophenol
58−90−2
30
Tetraethyl Lead
78−00−2
0.0001
Tetrahydrofuran
109−99−9
10
Thallic Oxide
1314−32−5
0.3
Thallium
7440−28−0
0.5
Thallium (I) Acetate
563−68−8
0.5
Thallium (I) Carbonate
6533−73−9
0.3
Thallium (I) Chloride
7791−12−0
0.3
Thallium (I) Nitrate
10102−45−1
0.5
Thallium Selenite
12039−52−0
0.5
Thallium (I) Sulfate
7446−18−6
0.075
Thiram
137−26−8
5
Toluene
108−88−3
300
1,2,4−Trichlorobenzene
120−82−1
20
Trichloromonofluoromethane
75−69−4
300
2.,4.,5−Trichlorophenol
95−95−4
100
Vanadium Pentoxide
1314−62−1
20
Warfarin
81−81−2
0.3
Xylenes
1330−20−7
80
Zinc Cyanide
557−21−1
50
Zinc Phosphide
1314−84−7
0.3
*The RAC for other ch. NR 661 Appendix VIII constituents not listed herein or in Appendix V is 0.1 ug/m3.
Section 88.   NR 666 Appendix V Table is amended to read:
Chapter NR 666
APPENDIX V
RISK SPECIFIC DOSES (10−5)
Constituent
CAS No.
Unit risk (m3/ug)
RsD (ug/m3)
Acrylamide
79−06−1
1.3E−03
7.7E−03
Acrylonitrile
107−13−1
6.8E−05
1.5E−01
Aldrin
309−00−2
4.9E−03
2.0E−03
Aniline
62−53−3
7.4E−06
1.4E+00
Arsenic
7440−38−2
4.3E−03
2.3E−03
Benz(a)anthracene
56−55−3
8.9E−04
1.1E−02
Benzene
71−43−2
8.3E−06
1.2E+00
Benzidine
92−87−5
6.7E−02
1.5E−04
Benzo(a)pyrene
50−32−8
3.3E−03
3.0E−03
Beryllium
7440−41−7
2.4E−03
4.2E−03
Bis(2−chloroethyl)ether
111−44−4
3.3E−04
3.0E−02
Bis(chloromethyl)ether
542−88−1
6.2E−02
1.6E−04
Bis(2−ethylhexyl)−phthalate
117−81−7
2.4E−07
4.2E+01
1,3−Butadiene
106−99−0
2.8E−04
3.6E−02
Cadmium
7440−43−9
1.8E−03
5.6E−03
Carbon Tetrachloride
56−23−5
1.5E−05
6.7E−01
Chlordane
57−74−9
3.7E−04
2.7E−02
Chloroform
67−66−3
2.3E−05
4.3E−01
Chloromethane
74−87−3
3.6E−06
2.8E+00
Chromium VI
7440−47−3
1.2E−02
8.3E−04
DDT
50−29−3
9.7E−05
1.0E−01
Dibenz(a,h)anthracene
53−70−3
1.4E−02
7.1E−04
1,2−Dibromo−3−chloropropane
96−12−8
6.3E−03
1.6E−03
1,2−Dibromoethane
106−93−4
2.2E−04
4.5E−02
1,1−Dichloroethane
75−34−3
2.6E−05
3.8E−01
1,2−Dichloroethane
107−06−2
2.6E−05
3.8E−01
1,1−Dichloroethylene
75−35−4
5.0E−05
2.0E−01
1,3−Dichloropropene
542−75−6
3.5E−01
2.9E−05
Dieldrin
60−57−1
4.6E−03
2.2E−03
Diethylstilbestrol
56−53−1
1.4E−01
7.1E−05
Dimethylnitrosamine
62−75−9
1.4E−02
7.1E−04
2,4−Dinitrotoluene
121−14−2
8.8E−05
1.1E−01
1,2−Diphenylhydrazine
122−66−7
2.2E−04
4.5E−02
1,4−Dioxane
123−91−1
1.4E−06
7.1E+00
Epichlorohydrin
106−89−8
1.2E−06
8.3E+00
Ethylene Oxide
75−21−8
1.0E−04
1.0E−01
Ethylene Dibromide
106−93−4
2.2E−04
4.5E−02
Formaldehyde
50−00−0
1.3E−05
7.7E−01
Heptachlor
76−44−8
1.3E−03
7.7E−03
Heptachlor Epoxide
1024−57−3
2.6E−03
3.8E−03
Hexachlorobenzene
118−74−1
4.9E−04
2.0E−02
Hexachlorobutadiene
87−68−3
2.0E−05
5.0E−01
Alpha−hexachloro−cyclohexane
319−84−6
1.8E−03
5.6E−03
Beta−hexachloro−cyclohexane
319−85−7
5.3E−04
1.9E−02
Gamma−hexachloro−cyclohexane
58−89−9
3.8E−04
2.6E−02
Hexachlorocyclo−hexane, Technical
5.1E−04
2.0E−02
Hexachlorodibenxo−p−dioxin Hexachlorodibenzo-p-dioxin (1,2 Mixture)
1.3E+0
7.7E−06
Hexachloroethane
67−72−1
4.0E−06
2.5E+00
Hydrazine
302−01−2
2.9E−03
3.4E−03
Hydrazine Sulfate
302−01−2
2.9E−03
3.4E−03
3−Methylcholanthrene
56−49−5
2.7E−03
3.7E−03
Methyl Hydrazine
60−34−4
3.1E−04
3.2E−02
Methylene Chloride
75−09−2
4.1E−06
2.4E+00
4,4’−Methylene−bis−2−chloroaniline
101−14−4
4.7E−05
2.1E−01
Nickel
7440−02−0
2.4E−04
4.2E−02
Nickel Refinery Dust
7440−02−0
2.4E−04
4.2E−02
Nickel Subsulfide
12035−72−2
4.8E−04
2.1E−02
2−Nitropropane
79−46−9
2.7E−02
3.7E−04
N−Nitroso−n−butylamine
924−16−3
1.6E−03
6.3E−03
N−Nitroso−n−methylurea
684−93−5
8.6E−02
1.2E−04
N−Nitrosodiethylamine
55−18−5
4.3E−02
2.3E−04
N−Nitrosopyrrolidine
930−55−2
6.1E−04
1.6E−02
Pentachloronitrobenzene
82−68−8
7.3E−05
1.4E−01
PCBs
1336−36−3
1.2E−03
8.3E−03
Pronamide
23950−58−5
4.6E−06
2.2E+00
Reserpine
50−55−5
3.0E−03
3.3E−03
2,3,7,8−Tetrachloro−dibenzo−p−dioxin
1746−01−6
4.5E+01
2.2E−07
1,1,2,2−Tetrachloroethane
79−34−5
5.8E−05
1.7E−01
Tetrachloroethylene
127−18−4
4.8E−07
2.1E+01
Thiourea
62−56−6
5.5E−04
1.8E−02
1,1,2−Trichloroethane
79−00−5
1.6E−05
6.3E−01
Trichloroethylene
79−01−6
1.3E−06
7.7E+00
2,4,6−Trichlorophenol
88−06−2
5.7E−06
1.8E+00
Toxaphene
8001−35−2
3.2E−04
3.1E−02
Vinyl Chloride
75−01−4
7.1E−06
1.4E+00
_Hlk153534558Section 89.   NR 668.04 (1) (c) (intro.) is amended to read:
NR 668.04 (1) (c) The impoundment meets the design requirements of under s. NR 664.0221 (3) or 665.0221 (1), regardless that the unit may not be new, expanded, or a replacement, and the impoundment is in compliance with applicable groundwater monitoring requirements of ch. under ch. NR 664 or 665 unless one of the following conditions are is met:
Section 90.   NR 668.07 (1) (d) Table row 8., (3) (b), and (4) (b) are amended to read:
NR 668.07 (1) (d)
Generator Paperwork Requirements Table
8. For contaminated soil subject to LDRs as provided in under s. NR 668.49 (1), the constituents subject to treatment as described in under s. NR 668.49 (4), and the following statement: This contaminated soil [does/does not] contain listed hazardous waste and [does/does not] exhibit a characteristic of hazardous waste and [is subject to/complies with with] the soil treatment standards as provided by under s. NR 668.49 (3) or the universal treatment standards
(3) (b) Test the waste, or an extract of the waste or treatment residue developed using test method 1311 (the Toxicity Characteristic Leaching Procedure), described in “Test Methods for Evaluating Solid Waste, Physical/Chemical Methods", EPA SW-846, incorporated by reference in under s. NR 660.11), to assure that the wastes or treatment residues are in compliance with the applicable treatment standards set forth in under subch. D. This testing shall be performed according to the frequency specified in the facility's waste analysis plan as required by s. NR 664.0013 or 665.0013.
(4) (b) The notification shall be updated if the debris is shipped to a different facility, and, for debris excluded under s. NR 661.0002 (5) (a) s. NR 661.0003 (6) (a), if a different type of debris is treated or if a different technology is used to treat the debris.
Section 91.   NR 668.14 (2) and (3) are amended to read:
NR 668.14 (2) Wastes which that are newly identified or listed under 42 USC 6921 after November 8, 1984, and stored in a surface impoundment that is newly subject to ch. 291, Stats., and chs. NR 660 to 673 as a result of the additional identification or listing, may continue to be stored in the surface impoundment for 48 months after the promulgation of the additional listing or characteristic, not withstanding notwithstanding that the waste is otherwise prohibited from land disposal, if the surface impoundment is in compliance with the requirements of under subch. F of ch. NR 665 within 12 months after promulgation of the new listing or characteristic.
(3) Wastes which that are newly identified or listed under 42 USC 6921 after November 8, 1984, and treated in a surface impoundment that is newly subject to ch. 291, Stats., and chs. NR 660 to 673 as a result of the additional identification or listing, may continue to be treated in that surface impoundment, not withstanding notwithstanding that the waste is otherwise prohibited from land disposal, if the surface impoundment is in compliance with subch. F of ch. NR 665 within 12 months after the promulgation of the new listing or characteristic. In addition, if the surface impoundment continues to treat hazardous waste after 48 months from promulgation of the additional listing or characteristic, it must shall then be in compliance with s. NR 668.04.
Section 92.   NR 668.42 (1) Table 1 is amended to read:
NR 668.42 (1) Table 1
Technology Codes and Description of Technology−Based Standards
Technology code
Description of technology−based standards
ADGAS:
AMLGM:
BIODG:
CARBN:
CHOXD:
CHRED:
CMBST:
DEACT:
FSUBS:
HLVIT:
IMERC:
INCIN:
LLEXT:
MACRO:
NEUTR:
NLDBR:
POLYM:
PRECP:
RBERY:
RCGAS:
RCORR:
RLEAD:
RMERC:
RMETL:
RORGS:
RTHRM:
RZINC:
STABL:
SSTRP:
WETOX:
WTRRX:
Venting of compressed gases into an absorbing or reacting media (i.e., solid or liquid)—venting can be accomplished through physical release utilizing valves or piping; physical penetration of the container; or penetration through detonation.
Amalgamation of liquid, elemental mercury contaminated with radioactive materials utilizing inorganic reagents such as copper, zinc, nickel, gold, and sulfur that result in a nonliquid, semi−solid amalgam and thereby reducing potential emissions of elemental mercury vapors to the air.
Biodegradation of organics or non−metallic inorganics (i.e., degradable inorganics that contain the elements of phosphorus, nitrogen, and sulfur) in units operated under either aerobic or anaerobic conditions such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic carbon can often be used as an indicator parameter for the biodegradation of many organic constituents that cannot be directly analyzed in wastewater residues).
Carbon adsorption (granulated or powdered) of non−metallic inorganics, organo−metallics, or organic constituents, operated such that a surrogate compound or indicator parameter has not undergone breakthrough (e.g., total organic carbon can often be used as an indicator parameter for the adsorption of many organic constituents that cannot be directly analyzed in wastewater residues). Breakthrough occurs when the carbon has become saturated with the constituent (or indicator parameter) and substantial change in adsorption rate associated with that constituent occurs.
Chemical or electrolytic oxidation utilizing the following oxidation reagents (or waste reagents) or combinations of reagents: (1) Hypochlorite (e.g., bleach); (2) chlorine; (3) chlorine dioxide; (4) ozone or UV (ultraviolet light) assisted ozone; (5) peroxides; (6) persulfates; (7) perchlorates; (8) permangantes; or (9) other oxidizing reagents of equivalent efficiency, performed in units operated such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic carbon can often be used as an indicator parameter for the oxidation of many organic constituents that cannot be directly analyzed in wastewater residues). Chemical oxidation specifically includes what is commonly referred to as alkaline chlorination.
Chemical reduction utilizing the following reducing reagents (or waste reagents) or combinations of reagents: (1) Sulfur dioxide; (2) sodium, potassium, or alkali salts or sulfites, bisulfites, metabisulfites, and polyethylene glycols (e.g., NaPEG and KPEG); (3) sodium hydrosulfide; (4) ferrous salts; or (5) other reducing reagents of equivalent efficiency, performed in units operated such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic halogens can often be used as an indicator parameter for the reduction of many halogenated organic constituents that cannot be directly analyzed in wastewater residues). Chemical reduction is commonly used for the reduction of hexavalent chromium to the trivalent state.
High temperature organic destruction technologies, such as combustion in incinerators, boilers, or industrial furnaces operated in accordance with the applicable requirements of subch. O of ch. NR 664 or 665, or subch. H of ch. NR 666, and in other units operated in accordance with applicable technical operating requirements; and certain non−combustive technologies, such as the catalytic extraction process.
Deactivation to remove the hazardous characteristics of a waste due to its ignitability, corrosivity, or reactivity.
Fuel substitution in units operated in accordance with applicable technical operating requirements.
Vitrification of high level mixed radioactive wastes in units in compliance with all applicable radioactive protection requirements under control of the nuclear regulatory commission.
Incineration of wastes containing organics and mercury in units operated according to the technical operating requirements of subch. O of ch. NR 664 and 665. All wastewater and nonwastewater residues derived from this process shall then comply with the corresponding treatment standards per waste code with consideration of any applicable subcategories (e.g., high or low mercury subcategories).
Incineration in units operated in accordance with the technical operating requirements of subch. O of ch. NR 664 and 665.
Liquid−liquid extraction (often referred to as solvent extraction) of organics from liquid wastes into an immiscible solvent for which the hazardous constituents have a greater solvent affinity, resulting in an extract high in organics that shall undergo either incineration, reuse as a fuel, or other recovery or reuse and a raffinate (extracted liquid waste) proportionately low in organics that shall undergo further treatment as specified in the standard.
Macroencapsulation with surface coating materials such as polymeric organics (e.g., resins and plastics) or with a jacket of inert inorganic materials to substantially reduce surface exposure to potential leaching media. Macroencapsulation specifically does not include any material that would be classified as a tank or container according to s. NR 660.10.
Neutralization with the following reagents (or waste reagents) or combinations of reagents: (1) acids; (2) bases; or (3) water (including wastewaters) resulting in a pH greater than 2 but less than 12.5 as measured in the aqueous residuals.
No land disposal based on recycling.
Formation of complex high−molecular weight solids through polymerization of monomers in high−TOC D001 non−wastewaters which are chemical components in the manufacture of plastics.
Chemical precipitation of metals and other inorganics as insoluble precipitates of oxides, hydroxides, carbonates, sulfides, sulfates, chlorides, fluorides, or phosphates. The following reagents (or waste reagents) are typically used alone or in combination: (1) lime (i.e., containing oxides or hydroxides of calcium or magnesium; (2) caustic (i.e., sodium or potassium hydroxides; (3) soda ash (i.e., sodium carbonate); (4) sodium sulfide; (5) ferric sulfate or ferric chloride; (6) alum; or (7) sodium sulfate. Additional floculating, coagulation or similar reagents or processes that enhance sludge dewatering characteristics are not precluded from use.
Thermal recovery of beryllium.
Recovery or reuse of compressed gases including techniques such as reprocessing of the gases for reuse or resale; filtering or adsorption of impurities; remixing for direct reuse or resale; and use of the gas as a fuel source.
Recovery of acids or bases utilizing one or more of the following recovery technologies: (1) distillation (i.e., thermal concentration); (2) ion exchange; (3) resin or solid adsorption; (4) reverse osmosis; or (5) incineration for the recovery of acid—Note: this does not preclude the use of other physical phase separation or concentration techniques such as decantation, filtration (including ultrafiltration), and centrifugation, when used in conjunction with the above listed recovery technologies.
Thermal recovery of lead in secondary lead smelters.
Retorting or roasting in a thermal processing unit capable of volatilizing mercury and subsequently condensing the volatilized mercury for recovery. The retorting or roasting unit (or facility) shall be subject to one or more of the following: (a) a National Emissions Standard for Hazardous Air Pollutants (NESHAP) for mercury; (b) a Best Available Control Technology (BACT) or a Lowest Achievable Emission Rate (LAER) standard for mercury imposed pursuant to a Prevention of Significant Deterioration (PSD) permit; or (c) a state permit that establishes emission limitations (within meaning of section 302 of the Clean Air Act) for mercury. All wastewater and nonwastewater residues derived from this process shall then comply with the corresponding treatment standards per waste code with consideration of any applicable subcategories (e.g., high or low mercury subcategories).
Recovery of metals or inorganics utilizing one or more of the following direct physical or removal technologies: (1) ion exchange; (2) resin or solid (i.e., zeolites) adsorption; (3) reverse osmosis; (4) chelation or solvent extraction; (5) freeze crystalization; (6) ultrafiltration and/or (7) simple precipitation (i.e., crystalization)—Note: This does not preclude the use of other physical phase separation or concentration techniques such as decantation, filtration (including ultrafiltration), and centrifugation, when used in conjunction with the above listed recovery technologies.
Recovery of organics utilizing one or more of the following technologies: (1) distillation; (2) thin film evaporation; (3) steam stripping; (4) carbon adsorption; (5) critical fluid extraction; (6) liquid−liquid extraction; (7) precipitation or crystallization (including freeze crystallization); or (8) chemical phase separation techniques (i.e., addition of acids, bases, demulsifiers, or similar chemicals);—Note: this does not preclude the use of other physical phase separation techniques such as a decantation, filtration (including ultrafiltration), and centrifugation, when used in conjunction with the above listed recovery technologies.
Thermal recovery of metals or inorganics from nonwastewaters in units identified as industrial furnaces according to s. NR 660.10 (a), (f), (g), (k) and (L) under the definition of “industrial furnaces”.
Resmelting in high temperature metal recovery units for the purpose of recovery of zinc.
Stabilization with the following reagents (or waste reagents) or combinations of reagents: (1) Portland cement; or (2) lime/pozzolans (e.g., fly ash and cement kiln dust)—this does not preclude the addition of reagents (e.g., iron salts, silicates, and clays) designed to enhance the set/cure time or compressive strength, or to overall reduce the leachability of the metal or inorganic.
Steam stripping of organics from liquid wastes utilizing direct application of steam to the wastes operated such in a manner that liquid and vapor flow rates, as well as, temperature and pressure ranges have been optimized, monitored, and maintained. These operating parameters are dependent upon the design parameters of the unit, such as, the number of separation stages and the internal column design. Thus, thus, resulting in a condensed extract high in organics that shall undergo either incineration, reuse as a fuel, or other recovery or reuse and an extracted wastewater that shall undergo further treatment as specified in the standard.
Wet air oxidation performed in units operated such that a surrogate compound or indicator parameter has been substantially reduced in concentration in the residuals (e.g., total organic carbon can often be used as an indicator parameter for the oxidation of many organic constituents that cannot be directly analyzed in wastewater residues).
Controlled reaction with water for highly reactive inorganic or organic chemicals with precautionary controls for protection of workers from potential violent reactions as well as precautionary controls for potential emissions of toxic or ignitable levels of gases released during the reaction.
Section 93.   NR 668.45 (4) Table 1 B. 2. a. is amended to read:
Table 1
Alternative Treatment Standards For Hazardous Debris
Technology description
Performance and/or design and operating standard
Contaminant restrictions2
B. Destruction Technologies:
2. Chemical Destruction
a. Chemical Oxidation: Chemical or electolytic electrolytic oxidation utilizing the following oxidation reagents (,or waste reagents), or combination of reagents—(1) hypochlorite (e.g., bleach); (2) chlorine; (3) chlorine dioxide; (4) ozone or UV (ultraviolet light) assisted ozone; (5) peroxides; (6) persulfates; (7) perchlorates; (8) permanganates; or (9) other oxidizing reagents of equivalent destruction efficiency4. Chemical oxidation specifically includes what is referred to as alkaline chlorination.
All Debris: Obtain an “Equivalent Technology” approval under s. NR 668.42 (2)8; treated debris shall be separated from treatment residuals using simple physical or mechanical means9, and, prior to further treatment, the residue shall meet the waste−specific treatment standards for organic compounds in the waste contaminating the debris. Brick, Cloth, Concrete, Paper, Pavement, Rock, Wood: Debris shall be no more than 1.2 cm (½ inch) in one dimension (i.e., thickness limit)5, except that this thickness limit may be waived under the “Equivalent Technology” approval.
All Debris: Metal contaminants.
Section 94.   NR 668.48 the header row of the Table is amended to read:
Section NR 668.48Universal Treatment Standards
Regulated constituent common name
Organic Constituents
CAS1 Number
Wastewater Standard
Nonwastewater Standard
Concentration2 in mg/ L2mg/L
Concentration3 in
mg/kg3mg/kg unless noted as “mg/L TCLP”
Acenaphthylene
208−96−8
0.059
3.4
Acenaphthene
83−32−9
0.059
3.4
Acetone
67−64−1
0.28
160
Acetonitrile
75−05−8
5.6
38
Acetophenone
96−86−2
0.010
9.7
2−Acetylaminofluorene
53−96−3
0.059
140
Acrolein
107−02−8
0.29
NA
Acrylamide
79−06−1
19
23
Acrylonitrile
107−13−1
0.24
84
Aldrin
309−00−2
0.021
0.066
4−Aminobiphenyl
92−67−1
0.13
NA
Aniline
62−53−3
0.81
14
o−Anisidine (2−methoxyaniline)
90−04−0
0.010
0.66
Anthracene
120−12−7
0.059
3.4
Aramite
140−57−8
0.36
NA
alpha−BHC
319−84−6
0.00014
0.066
beta−BHC
319−85−7
0.00014
0.066
delta−BHC
319−86−8
0.023
0.066
gamma−BHC
58−89−9
0.0017
0.066
Benzene
71−43−2
0.14
10
Benz(a)anthracene
56−55−3
0.059
3.4
Benzal chloride
98−87−3
0.055
6.0
Benzo(b)fluoranthene (difficult to distinguish from benzo(k)fluoranthene)
205−99−2
0.11
6.8
Benzo(k)fluoranthene (difficult to distinguish from benzo(b)fluoranthene)
207−08−9
0.11
6.8
Benzo(g,h,i)perylene
191−24−2
0.0055
1.8
Benzo(a)pyrene
50−32−8
0.061
3.4
Bromodichloromethane
75−27−4
0.35
15
Bromomethane/Methyl bromide
74−83−9
0.11
15
4−Bromophenyl phenyl ether
101−55−3
0.055
15
n−Butyl alcohol
71−36−3
5.6
2.6
Butyl benzyl phthalate
85−68−7
0.017
28
2−sec−Butyl−4,6−dinitrophenol/Dinoseb
88−85−7
0.066
2.5
Carbon disulfide
75−15−0
3.8
4.8 mg/L TCLP
Carbon tetrachloride
56−23−5
0.057
6.0
Chlordane (alpha and gamma isomers)
57−74−9
0.0033
0.26
p−Chloroaniline
106−47−8
0.46
16
Chlorobenzene
108−90−7
0.057
6.0
Chlorobenzilate
510−15−6
0.10
NA
2−Chloro−1,3−butadiene
126−99−8
0.057
0.28
Chlorodibromomethane
124−48−1
0.057
15
Chloroethane
75−00−3
0.27
6.0
bis(2−Chloroethoxy)methane
111−91−1
0.036
7.2
bis(2−Chloroethyl)ether
111−44−4
0.033
6.0
Chloroform
67−66−3
0.046
6.0
bis(2−Chloroisopropyl)ether
39638−32−9
0.055
7.2
p−Chloro−m−cresol
59−50−7
0.018
14
2−Chloroethyl vinyl ether
110−75−8
0.062
NA
Chloromethane/Methyl chloride
74−87−3
0.19
30
2−Chloronaphthalene
91−58−7
0.055
5.6
2−Chlorophenol
95−57−8
0.044
5.7
3−Chloropropylene
107−05−1
0.036
30
Chrysene
218−01−9
0.059
3.4
p−Cresidine
120−71−8
0.010
0.66
o−Cresol
95−48−7
0.11
5.6
m−Cresol (difficult to distinguish from p−cresol)
108−39−4
0.77
5.6
p−Cresol (difficult to distinguish from m−cresol)
106−44−5
0.77
5.6
Cyclohexanone
108−94−1
0.36
0.75 mg/L TCLP
o,p’−DDD
53−19−0
0.023
0.087
p,p’−DDD
72−54−8
0.023
0.087
o,p’−DDE
3424−82−6
0.031
0.087
p,p’−DDE
72−55−9
0.031
0.087
o,p’−DDT
789−02−6
0.0039
0.087
p,p’−DDT
50−29−3
0.0039
0.087
Dibenz(a,h)anthracene
53−70−3
0.055
8.2
Dibenz(a,e)pyrene
192−65−4
0.061
NA
1,2−Dibromo−3−chloropropane
96−12−8
0.11
15
1,2−Dibromoethane/Ethylene dibromide
106−93−4
0.028
15
Dibromomethane
74−95−3
0.11
15
m−Dichlorobenzene
541−73−1
0.036
6.0
o−Dichlorobenzene
95−50−1
0.088
6.0
p−Dichlorobenzene
106−46−7
0.090
6.0
Dichlorodifluoromethane
75−71−8
0.23
7.2
1,1−Dichloroethane
75−34−3
0.059
6.0
1,2−Dichloroethane
107−06−2
0.21
6.0
1,1−Dichloroethylene
75−35−4
0.025
6.0
trans−1,2−Dichloroethylene
156−60−5
0.054
30
2,4−Dichlorophenol
120−83−2
0.044
14
2,6−Dichlorophenol
87−65−0
0.044
14
2,4−Dichlorophenoxyacetic acid/2,4−D
94−75−7
0.72
10
1,2−Dichloropropane
78−87−5
0.85
18
cis−1,3−Dichloropropylene
10061−01−5
0.036
18
trans−1,3−Dichloropropylene
10061−02−6
0.036
18
Dieldrin
60−57−1
0.017
0.13
Diethyl phthalate
84−66−2
0.20
28
p−Dimethylaminoazobenzene
60−11−7
0.13
NA
2,4−Dimethylanaline (2,4−xylidine)
95−68−1
0.010
0.66
2−4−Dimethyl phenol
105−67−9
0.036
14
Dimethyl phthalate
131−11−3
0.047
28
Di−n−butyl phthalate
84−74−2
0.057
28
1,4−Dinitrobenzene
100−25−4
0.32
2.3
4,6−Dinitro−o−cresol
534−52−1
0.28
160
2,4−Dinitrophenol
51−28−5
0.12
160
2,4−Dinitrotoluene
121−14−2
0.32
140
2,6−Dinitrotoluene
606−20−2
0.55
28
Di−n−octyl phthalate
117−84−0
0.017
28
Di−n−propylnitrosamine
621−64−7
0.40
14
1,4−Dioxane
123−91−1
12.0
170
Diphenylamine (difficult to distinguish from diphenylnitrosamine)
122−39−4
0.92
13
Diphenylnitrosamine (difficult to distinguish from diphenylamine)
86−30−6
0.92
13
1,2−Diphenylhydrazine
122−66−7
0.087
NA
Disulfoton
298−04−4
0.017
6.2
Endosulfan I
959−98−8
0.023
0.066
Endosulfan II
33213−65−9
0.029
0.13
Endosulfan sulfate
1031−07−8
0.029
0.13
Endrin
72−20−8
0.0028
0.13
Endrin aldehyde
7421−93−4
0.025
0.13
Ethyl acetate
141−78−6
0.34
33
Ethyl benzene
100−41−4
0.057
10
Ethyl cyanide/Propanenitrile
107−12−0
0.24
360
Ethyl ether
60−29−7
0.12
160
bis(2−Ethylhexyl)phthalate
117−81−7
0.28
28
Ethyl methacrylate
97−63−2
0.14
160
Ethylene oxide
75−21−8
0.12
NA
Famphur
52−85−7
0.017
15
Fluoranthene
206−44−0
0.068
3.4
Fluorene
86−73−7
0.059
3.4
Heptachlor
76−44−8
0.0012
0.066
Heptachlor epoxide
1024−57−3
0.016
0.066
1,2,3,4,6,7,8−Heptachlorodibenzo−p−dioxin(1,2,3,4,6,7,8−HpCDD)
35822−46−9
0.000035
0.0025
1,2,3,4,6,7,8−Heptachlorodibenzofuran (1,2,3,4,6,7,8−HpCDF)
67562−39−4
0.000035
0.0025
1,2,3,4,7,8,9−Heptachlorodibenzofuran (1,2,3,4,7,8,9−HpCDF)
55673−89−7
0.000035
0.0025
Hexachlorobenzene
118−74−1
0.055
10
Hexachlorobutadiene
87−68−3
0.055
5.6
Hexachlorocyclopentadiene
77−47−4
0.057
2.4
HxCDDs (All Hexachlorodibenzo−p−dioxins)
NA
0.000063
0.001
HxCDFs (All Hexachlorodibenzofurans)
NA
0.000063
0.001
Hexachloroethane
67−72−1
0.055
30
Hexachloropropylene
1888−71−7
0.035
30
Indeno (1,2,3−c,d) pyrene
193−39−5
0.0055
3.4
Iodomethane
74−88−4
0.19
65
Isobutyl alcohol
78−83−1
5.6
170
Isodrin
465−73−6
0.021
0.066
Isosafrole
120−58−1
0.081
2.6
Kepone
143−50−0
0.0011
0.13
Methacrylonitrile
126−98−7
0.24
84
Methanol
67−56−1
5.6
0.75 mg/L TCLP
Methapyrilene
91−80−5
0.081
1.5
Methoxychlor
72−43−5
0.25
0.18
3−Methylcholanthrene
56−49−5
0.0055
15
4,4−Methylene bis(2−chloroaniline)
101−14−4
0.50
30
Methylene chloride
75−09−2
0.089
30
Methyl ethyl ketone
78−93−3
0.28
36
Methyl isobutyl ketone
108−10−1
0.14
33
Methyl methacrylate
80−62−6
0.14
160
Methyl methansulfonate
66−27−3
0.018
NA
Methyl parathion
298−00−0
0.014
4.6
Naphthalene
91−20−3
0.059
5.6
2−Naphthylamine
91−59−8
0.52
NA
o−Nitroaniline
88−74−4
0.27
14
p−Nitroaniline
100−01−6
0.028
28
Nitrobenzene
98−95−3
0.068
14
5−Nitro−o−toluidine
99−55−8
0.32
28
o−Nitrophenol
88−75−5
0.028
13
p−Nitrophenol
100−02−7
0.12
29
N−Nitrosodiethylamine
55−18−5
0.40
28
N−Nitrosodimethylamine
62−75−9
0.40
2.3
N−Nitroso−di−n−butylamine
924−16−3
0.40
17
N−Nitrosomethylethylamine
10595−95−6
0.40
2.3
N−Nitrosomorpholine
59−89−2
0.40
2.3
N−Nitrosopiperidine
100−75−4
0.013
35
N−Nitrosopyrrolidine
930−55−2
0.013
35
1,2,3,4,6,7,8,9−Octachlorodibenzo−p−dioxin (OCDD)
3268−87−9
0.000063
0.005
1,2,3,4,6,7,8,9−Octachlorodibenzofuran (OCDF)
39001−02−0
0.000063
0.005
Parathion
56−38−2
0.014
4.6
Total PCBs (sum of all PCB isomers, or all Aroclors)8
1336−36−3
0.10
10
Pentachlorobenzene
608−93−5
0.055
10
PeCDDs (All Pentachlorodibenzo−p−dioxins)
NA
0.000063
0.001
PeCDFs (All Pentachlorodibenzofurans)
NA
0.000035
0.001
Pentachloroethane
76−01−7
0.055
6.0
Pentachloronitrobenzene
82−68−8
0.055
4.8
Pentachlorophenol
87−86−5
0.089
7.4
Phenacetin
62−44−2
0.081
16
Phenanthrene
85−01−8
0.059
5.6
Phenol
108−95−2
0.039
6.2
1,3−Phenylenediamine
108−45−2
0.010
0.66
Phorate
298−02−2
0.021
4.6
Phthalic acid
100−21−0
0.055
28
Phthalic anhydride
85−44−9
0.055
28
Pronamide
23950−58−5
0.093
1.5
Pyrene
129−00−0
0.067
8.2
Pyridine
110−86−1
0.014
16
Safrole
94−59−7
0.081
22
Silvex/2,4,5−TP
93−72−1
0.72
7.9
1,2,4,5−Tetrachlorobenzene
95−94−3
0.055
14
TCDDs (All Tetrachlorodibenzo−p−dioxins)
NA
0.000063
0.001
TCDFs (All Tetrachlorodibenzofurans)
NA
0.000063
0.001
1,1,1,2−Tetrachloroethane
630−20−6
0.057
6.0
1,1,2,2−Tetrachloroethane
79−34−5
0.057
6.0
Tetrachloroethylene
127−18−4
0.056
6.0
2,3,4,6−Tetrachlorophenol
58−90−2
0.030
7.4
Toluene
108−88−3
0.080
10
Toxaphene
8001−35−2
0.0095
2.6
Tribromomethane/Bromoform
75−25−2
0.63
15
1,2,4−Trichlorobenzene
120−82−1
0.055
19
1,1,1−Trichloroethane
71−55−6
0.054
6.0
1,1,2−Trichloroethane
79−00−5
0.054
6.0
Trichloroethylene
79−01−6
0.054
6.0
Trichloromonofluoromethane
75−69−4
0.020
30
2,4,5−Trichlorophenol
95−95−4
0.18
7.4
2,4,6−Trichlorophenol
88−06−2
0.035
7.4
2,4,5−Trichlorophenoxyacetic acid/2,4,5−T
93−76−5
0.72
7.9
1,2,3−Trichloropropane
96−18−4
0.85
30
1,1,2−Trichloro−1,2,2−trifluoroethane
76−13−1
0.057
30
tris−(2,3−Dibromopropyl) phosphate
126−72−7
0.11
0.10
Vinyl chloride
75−01−4
0.27
6.0
Xylenes−mixed isomers (sum of o−, m−, and p−xylene concentrations)
1330−20−7
0.32
30
Inorganic Constituents
Antimony
7440−36−0
1.9
1.15 mg/L TCLP
Arsenic
7440−38−2
1.4
5.0 mg/L TCLP
Barium
7440−39−3
1.2
21 mg/L TCLP
Beryllium
7440−41−7
0.82
1.22 mg/L TCLP
Cadmium
7440−43−9
0.69
0.11 mg/L TCLP
Chromium (Total)
7440−47−3
2.77
0.60 mg/L TCLP
Cyanides (Total)4
57−12−5
1.2
590
Cyanides (Amenable)4
57−12−5
0.86
30
Fluoride5
16984−48−8
35
NA
Lead
7439−92−1
0.69
0.75 mg/L TCLP
Mercury − Nonwastewater from Retort
7439−97−6
NA
0.20 mg/L TCLP
Mercury − All Others
7439−97−6
0.15
0.025 mg/L TCLP
Nickel
7440−02−0
3.98
11. mg/L TCLP
Selenium7
7782−49−2
0.82
5.7 mg/L TCLP
Silver
7440−22−4
0.43
0.14 mg/L TCLP
Sulfide5
18496−25−8
14
NA
Thallium
7440−28−0
1.4
0.20 mg/L TCLP
Vanadium5
7440−62−2
4.3
1.6 mg/L TCLP
Zinc5
7440−66−6
2.61
4.3 mg/L TCLP
Section 95.   NR 668.50 (3) is amended to read:
NR 668.50 (3) A An owner or operator of a treatment, storage, or disposal facility may store the wastes beyond one year; however, the owner or operator bears the burden of proving that the storage was solely for the purpose of accumulation of quantities of hazardous waste as are necessary to facilitate proper recovery, treatment, or disposal.
Section 96.   NR 670.001 (3) is amended to read:
NR 670.001 (3) Scope of the license requirement. Section 291.25 (2), Stats., requires a license for the operation of a treatment, storage or disposal facility where when any hazardous waste identified or listed in under ch. NR 661 is managed. The terms “treatment," “storage," “ disposal," and “hazardous waste" are defined in under s. NR 660.10. Owners and operators of hazardous waste management units shall have licenses during the active life (, including the closure period), of the unit. Owners and operators of surface impoundments, landfills, and waste pile units that received waste after July 26, 1982, or that certified closure (, according to s. NR 665.0115), after January 26, 1983, shall have long-term care licenses, unless they the owners and operators demonstrate closure by removal or decontamination as provided under pars. (e) and (f), or obtain an enforceable document in lieu of a long-term care license, as provided under par. (g). If a long- term long-term care license is required, the license shall address applicable ch. NR 664 groundwater monitoring, unsaturated zone monitoring, corrective action, and long-term care requirements of this chapter. The denial of a license for the active life of a hazardous waste management facility or unit does not affect the requirement to obtain a long-term care license under this section.
_Hlk167100635Section 97.   NR 670.018 (2) and (7) are amended to read:
NR 670.018 (2) If an exemption is sought to s. NR 664.0251 and subch. F of ch. NR 664 as provided by s. NR 664.0250 (3) or 664.0090 664.0090 (2) (b), an explanation of how the standards of under s. NR 664.0250 (3) will be complied with or detailed plans and an engineering report describing how s. NR 664.0090 (2) (b) will be met.
(7) If incompatible wastes, or incompatible wastes and materials, will be place placed in a waste pile, an explanation of how s. NR 664.0257 will be complied with.
Section 98.   NR 670.025 (5) (c) is amended to read:
NR 670.025 (5) (c) A design analysis, specifications, drawings, schematics, and piping and instrumentation diagrams based on the appropriate sections of ATPI APTI Course 415: Control of Gaseous Emissions, incorporated by reference in s. NR 660.11, or other engineering texts acceptable to the department that present basic control device design information. The design analysis shall address the vent stream characteristics and control device operation parameters as specified in s. NR 664.1035 (2) (d) 3.
Section 99.   NR 670.041 (3) is amended to read:
NR 670.041 (3) Facility siting. Suitability of the facility location will not be considered at the time of license modification or revocation and reissuance unless new information or standards indicate that a threat to human health or the environmental environment exists which was unknown at the time of license issuance.
Section 100.   NR 670.042 (1) (b) and (2) (f) 1. (intro.) are amended to read:
NR 670.042 (1) (b) Class 1 license modifications identified in under ch. NR 670 as Class 1-1 by a footnote may be made only with the prior written approval of the department.
(2) (f) 1. No later than 90 days after receipt of the notification modification request, the department shall do one of the following:
Section 101.   NR 670.050 (1) is amended to read:
_Hlk149208936NR 670.050 (1) Operating licenses shall be effective for a fixed term of no more than 10 years, but are subject to annual renewal operating license fees during that term.
Section 102.   NR 670.235 (1) (b) (intro.) and (2) (b) are amended to read:
NR 670.235 (1) (b) The owner or operator of an incinerator, cement kiln or, lightweight aggregate kiln, solid fuel boiler, liquid fuel boiler, or hydrochloric acid production furnace that has conducted a comprehensive performance test and submitted to the department a notification of compliance documenting compliance with the standards of under 40 CFR part 63, subpart EEE may request in the application to reissue the license for the combustion unit that the owner or operator control emissions from startup, shutdown, and malfunction events under any of the following options:
(2) (b) Operations under a subsequent operating license. When an owner or operator of an incinerator, cement kiln or, lightweight aggregate kiln, solid fuel boiler, liquid fuel boiler, or hydrochloric acid production furnace that is operating under the interim license standards of under ch. NR 665 or 666 submits an operating license application, the owner or operator may request that the department control emissions from startup, shutdown, and malfunction events under any of the options provided by sub. (1) (b) 1.2., or 3.
Section 103.   NR 670 Appendix I Table L. 9. and O. 1. are amended to read:
Chapter NR 670
APPENDIX I
CLASSIFICATION OF LICENSE MODIFICATION
Modifications
Class
L. Incinerators, Boilers and Industrial Furnaces:
9. Changes to hazardous waste license provisions needed to support transition to 40 CFR part 63 (Subpart EEE—National Emission Standards for Hazardous Air Pollutants from Hazardous Waste Combustors), provided the procedures of under s. NR 670.042 (11) are followed.
11 1-1
O. Burden Reduction:
1. Development of one contingency plan based on Integrated Contingency Plan Guidance pursuant to s. NR 664.0052 (2)
11 1-1
Section 104.   NR 679.01 (12) (Note) is created to read:
NR 679.01 (12) Note: Examples of materials that, when used, qualify as used oil: antifreeze, compressor oils, coolants, copper and aluminum drawing solutions, electrical insulating oil, emulsions when used as lubricants, engine oil, heating media, grease, hydraulic fluid, industrial process oils, laminating oils, metal-working fluids and cutting oils, mineral oil, oils used as buoyant, refrigeration oil, transmission fluid, used oil residues and sludges from the storage, processing, and re-refining of used oils (when recycled by burning for energy recovery).
Examples of materials that, when used, do not qualify as used oil: animal and vegetable oil even when used as a lubricant, kerosene, oils that have not been used, solvents when used to solubilize or mobilize, spills of virgin fuel oil, used oil re-refining distillation bottoms that are used as feedstock to manufacture asphalt products, and waste oil resulting from cleanout of virgin fuel storage tank bottoms. Oils that do not meet EPA's definition of used oil can still pose a threat to the environment when disposed of and could be subject to the RCRA regulations for hazardous waste management.
Section 105.   NR 679.10 (2) (b) (intro.) is amended to read:
NR 679.10 (2) (b) Characteristic hazardous waste. Mixtures of used oil and hazardous waste that solely exhibits exhibit any hazardous waste characteristics identified in under subch. C of ch. NR 661, and mixtures of used oil and hazardous waste that is listed in under subch. D of ch. NR 661 solely because it exhibits any hazardous waste characteristics identified in under subch. C of ch. NR 661, are regulated as one of the following:
Section 106.   NR 679.11 (intro.) and Table 1 are amended to read:
NR 679.11 Used oil specifications. Used oil burned for energy recovery, and any fuel produced from used oil by processing, blending or other treatment, is regulated under this chapter unless it is shown not to exceed any of the allowable levels of the constituents and properties in the specification shown in Table 1. Once used oil that is to be burned for energy recovery has been shown not to exceed any specification allowable level and the person making that showing complies with ss. NR 679.72679.73, and 679.74 (2), the used oil is no longer regulated under this chapter.
Table 1 −
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